Achiral endohedral functionality provides stereochemical control in Fe(II)-based self-assemblies.
نویسندگان
چکیده
Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 16 شماره
صفحات -
تاریخ انتشار 2013